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Analysis of institutional authors

Santafé-Moros, AAuthorGozálvez-Zafrilla, JmCorresponding Author

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December 22, 2025
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Article

Methane dehydroaromatization in a catalytic co-ionic membrane reactor: A parametric study with finite element analysis

Publicated to: Chemical Engineering Journal Advances. 24 100906- - 2025-11-01 24(), DOI: 10.1016/j.ceja.2025.100906

Authors:

Catalán-Martínez, D; Santafé-Moros, A; Kjolseth, C; Gozálvez-Zafrilla, JM; Serraa, JM
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Affiliations

Coorstek Membrane Sci, Forskningsparken,Gaustadalleen 21 - Author
Univ Politecn Valencia Consejo Super Invest Cient, Inst Tecnol Quim, Avda Naranjos S-N - Author
Univ Politecn Valencia, Inst Ind Radiophys & Environm Safety ISIRYM, C-Camino Vera S-N - Author
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Abstract

Methane dehydroaromatization produces benzene from natural gas or biomethane in one step but faces thermodynamic and catalyst deactivation challenges due to coke formation. Co-ionic conducting membrane reactors mitigate these issues by extracting hydrogen and injecting oxide ions, boosting benzene yield, and suppressing coke. This study develops a finite element computational model that integrates gas flow, species transport, catalytic reactions, and electrochemical effects. Using kinetic parameters fitted from experimental data, the model analyses the impact of electrochemical ion pumping, feed rate, space velocity, and geometry on benzene yield and coke suppression. Results show that hydrogen generation is mainly limited by ethylene formation kinetics. Even so, for the high catalyst loads studied (GSHV = 500 NmL/(g & sdot;h)), methane conversion higher than 50 % and benzene selectivity of 80 % are achieved. Parametric studies identified optimal geometry and conditions that allow over 95 % hydrogen extraction, shifting conversion toward benzene formation. Additionally, the model pinpoints conditions where local steam suppresses coke without causing catalyst deactivation via oxidation or reforming reactions.
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Keywords

AromatizationBenzeneChemicalsDirect conversionElectrochemical reactorFuelsHydrogenHydrogen extractionMdaMethaneMo/hzsm-5 catalystModellingNatural-gasProton conductorRu-mo/hzsm-5Temperatures

Quality index

Bibliometric impact. Analysis of the contribution and dissemination channel

The work has been published in the journal Chemical Engineering Journal Advances due to its progression and the good impact it has achieved in recent years, according to the agency WoS (JCR), it has become a reference in its field. In the year of publication of the work, 2025, it was in position 26/176, thus managing to position itself as a Q1 (Primer Cuartil), in the category Engineering, Chemical.

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Impact and social visibility

From the perspective of influence or social adoption, and based on metrics associated with mentions and interactions provided by agencies specializing in calculating the so-called "Alternative or Social Metrics," we can highlight as of 2026-04-03:

  • The use of this contribution in bookmarks, code forks, additions to favorite lists for recurrent reading, as well as general views, indicates that someone is using the publication as a basis for their current work. This may be a notable indicator of future more formal and academic citations. This claim is supported by the result of the "Capture" indicator, which yields a total of: 2 (PlumX).

With a more dissemination-oriented intent and targeting more general audiences, we can observe other more global scores such as:

    It is essential to present evidence supporting full alignment with institutional principles and guidelines on Open Science and the Conservation and Dissemination of Intellectual Heritage. A clear example of this is:

    • The work has been submitted to a journal whose editorial policy allows open Open Access publication.
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    Leadership analysis of institutional authors

    This work has been carried out with international collaboration, specifically with researchers from: Norway.

    There is a significant leadership presence as some of the institution’s authors appear as the first or last signer, detailed as follows: First Author (Catalán-Martínez, D) and Last Author (Serraa, JM).

    the author responsible for correspondence tasks has been Gozálvez Zafrilla, José Marcial.

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